Mensuration of the Dried Collodion Membrane (calcu- Lation of Dimensions and of Relations

نویسندگان

  • A. A. WEECH
  • L. MICHAELIS
چکیده

In a previous paper of this series a flat form of the dried collodion membrane and its method of preparation was described (1). As this form of membrane presented certain advantages in durability and convenience of manipulation over the previously used bag membranes, it was the type used in most of the subsequent investigations. Electric transfer experiments in which relatively strong electric currents were used (2, 3) and diffusion experiments continued over a period of several months (4) were both made possible because of the resistant and stable properties of these membranes. In experiments to be reported on in the near future the same type of membrane was used for conductivity measurements. In view of the many experiments made with these membranes it has seemed desirable to publish a brief account of measurements of the dimensions and physical properties of some of them. Such measurements are necessary when one wishes to compare diffusion rates, conductivity values, etc., with results obtained with other types of membranes. In the last paper of this series (4), dealing with the diffusion of non-electrolytes, the rates of diffusion of acetone, glycerol, urea and glucose were measured for a number of these membranes but as the result desired was a ratio of the rates at which different substances diffused it was not necessary to reduce the results with any one membrane to terms of unit area and thickness. Nevertheless some points of interest can be brought out by so doing as will be shown presently. The membranes used in the present study were selected from those 221

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تاریخ انتشار 2003